Publications & patents

Publications

  1. Y. Wang, V. Raj, K. G. Naik, B. S. Vishnugopi, J. Cho, M. Nguyen, E. A. Recker, Y. Su, H.Celio, A. Dolocan, Z. A. Page, J. Watt, G. Henkelman, Q.  H. Tu, P. P. Mukherjee, D. Mitlin, “Control of Two Solid Electrolyte Interphases at the Negative Electrode of an Anode‐Free All Solid‐State Battery based on Argyrodite Electrolyte“, Advanced Materials, 2410948
  2. S. E. Sandoval, C. G. Haslam, B. S Vishnugopi, D. W. Liao, J. S. Yoon, S. H. Park, Y. Wang, D. Mitlin, K. B. Hatzell, D. J. Siegel, P. P. Mukherjee, N. P. Dasgupta, J. Sakamoto, M. T.  McDowell, “Electro-chemo-mechanics of anode-free solid-state batteries“, Nature Materials, 2025
  3. A. G. Paul-Orecchio, L. Stockton, N. Barichello, A. Petersen, A. Dolocan, Y. Wang, D. Mitlin, C. B. Mullins, “Dual-Function Alloying Nitrate Additives Stabilize Fast-Charging Lithium Metal Batteries”, ACS Applied Materials & Interfaces, 2024, 16 39341
  4. Y. Wang, H. Hao, K. Naik, B. Vishnugopi, C. Fincher, Q. Yan, V. Raj, H. Celio, G. Yang, H. Fang, Y. Chiang, F. Perras, P. Jena, J. Watt, P. Mukherjee, D. Mitlin, “Mechanical Milling–Induced Microstructure Changes in Argyrodite LPSCl Solid‐State Electrolyte Critically Affect Electrochemical Stability”, Advanced Energy Materials, 2024, 14, 202304530
  5. P. Liu, H. Hao, A. Singla, B. Vishnugopi, J. Watt, P. Mukherjee, D. Mitlin, “Alumina‐Stabilized SEI and CEI in Potassium Metal Batteries”, Angewandte Chemie International Edition, 2024, 63, e202402214
  6. D. Yang, J. Wang, C. Lou, M. Li, C. Zhang, A. Ramon, C. Li, M. Tang, G. Henkelman, M. Xu, J. Li, J. Llorca, J. Arbiol, D. Mitlin, G. Zhou, A. Cabot, “Single-Atom Catalysts with Unsaturated Co–N2 Active Sites Based on a C2N 2D-Organic Framework for Efficient Sulfur Redox Reaction”,
    ACS Energy Letters, 2024, 9, 2083-2091
  7. V. Raj, K. G. Naik, B. S. Vishnugopi, A. K. Rana, A. S. Manning, S. R. Mahapatra, K. R. Varun, V. Singh, A. Nigam, J. D.  McBrayer, P. P Mukherjee, N. B.  Aetukuri, D. Mitlin, “Dendrite Growth—Microstructure—Stress—Interrelations in Garnet Solid‐State Electrolyte”,
    Advanced Energy Materials, 2024, 14, 15, 2303062
  8. W. Liu, Y. Luo, Y. Hu, Z. Chen, Q .Wang, Y. Chen, N. Iqbal, D. Mitlin, “Interrelation Between External Pressure, SEI Structure, and Electrodeposit Morphology in an Anode‐Free Lithium Metal Battery”, Advanced Energy Materials, 2024, 14, 5, 2302261
  9. W. Song, C. Xiao, J. Ding, Z. Huang, X. Yang, T. Zhang, D. Mitlin, W. Hu, “Review of carbon support coordination environments for single metal atom electrocatalysts (SACS)”, Advanced Materials, 2024,36, 2301477
  10. P. Chien, B. Ouyang, X. Feng, L. Dong, D. Mitlin, J. Nanda, J. Liu, “Promoting Fast Ion Conduction in Li-Argyrodite through Lithium Sublattice Engineering”, Chemistry of Materials, 2024, 36, 382−393
  11. W. Liu, Y. Luo, Y. Hu, Z .Chen, Q. Wang, Y. Chen, N. Iqbal, D. Mitlin, “Interrelation Between External Pressure, SEI Structure, and Electrodeposit Morphology in an Anode‐Free Lithium Metal Battery“, Advanced Energy Materials, 2024, 14, 2302261
  12. H. Hao, Y. Liu, S.M. Greene, G. Yang, K.G. Naik, B.S. Vishnugopi, Y. Wang, H. Celio, A. Dolocan, W. Tsai, R. Fang, J. Watt, P. Mukherjee, D. Siegel, D. Mitlin, “Tuned Reactivity at the Lithium Metal–Argyrodite Solid State Electrolyte Interphase“, Advanced Energy Materials, 2023, 13, 2301338
  13. Y. Wang, H. Dong, N. Katyal, B. Vishnugopi, M. Singh, H. Hao, Y. Liu, P. Liu, P. Mukherjee, G. Henkelman, J. Watt, D. Mitlin, “Intermetallics Based on Sodium Chalcogenides Promote Stable Electrodeposition–Electrodissolution of Sodium Metal Anodes”, Advanced Energy Materials, 2023, 13, 2204402
  14. W. Song, C. Xiao, J. Ding, Z. Huang, X. Yang, T. Zhang, D. Mitlin, W. Hu, “Review of Carbon Support Coordination Environments for Single Metal Atom Electrocatalysts (SACS)”, Advanced Materials, 2024, 36, 2301477
  15. P. Liu, D. Yen, B. Vishnugopi, V. Kankanallu, D. Gürsoy, M. Ge, J. Watt, P. Mukherjee, Y. Chen-Wiegart, D. Mitlin, “Influence of Potassium Metal–Support Interactions on Dendrite Growth”, Angewandte Chemie International Edition, 2023, 62, e202300943
  16. Y. Wang, Y. Liu, M. Nguyen, J. Cho, N. Katyal, B. Vishnugopi, H. Hao, R. Fang, N. Wu, P. Liu, P. Mukherjee, J. Nanda, G. Henkelman, J. Watt, D. Mitlin, “Stable Anode‐Free All‐Solid‐State Lithium Battery through Tuned Metal Wetting on the Copper Current Collector”, Advanced Materials, 2023, 35, 2206762
  17. Y. Liu, R. Fang, D. Mitlin, “NASICON solid electrolyte coated by indium film for all-solid-state Li-metal batteries”, Tungsten, 2022, 1-7
  18. J. Ma, X. Feng, Y. Wu, Y. Wang, P. Liu, K. Shang, H. Jiang, X. Hou, D. Mitlin, H. Xiang, “Stable sodium anodes for sodium metal batteries (SMBs) enabled by in-situ formed quasi solid-state polymer electrolyte”, Journal of Energy Chemistry, 2023, 77, 290-299
  19. Z. Huang, H. Li, Z. Yang, H. Wang, J. Ding, L. Xu, Y. Tian, D. Mitlin, J. Ding, W. Hu, “Nanosecond laser lithography enables concave-convex zinc metal battery anodes with ultrahigh areal capacity”, Energy Storage Materials, 2022, 51, 273-285
  20. D. Yang, M. Li, X. Zheng, X. Han, C. Zhang, J. Biendicho, J. Llorca, J. Wang, H. Hao, J. Li, G. Henkelman, J. Arbiol, J. Morante, D. Mitlin, S. Chou, A. Cabot, “Phase Engineering of Defective Copper Selenide toward Robust Lithium–Sulfur Batteries”, ACS Nano, 2022, 16, 7, 11102-11114
  21. X. Guo, Y. Liu, X. Zhang, Z. Ju, Y. Li, D. Mitlin, G. Yu, “Revealing the Solid-State Electrolyte Interfacial Stability Model with Na–K Liquid Alloy”, Angewandte Chemie International Edition, 2022, e202203409
  22. H. Hao, Y. Wang, N. Katyal, G. Yang, H. Dong, P. Liu, S. Hwang, J. Mantha, G. Henkelman, Y. Xu, J. Boscoboinik, J. Nanda, D. Mitlin, “Molybdenum Carbide Electrocatalyst in‐situ Embedded in Porous Nitrogen‐rich Carbon Nanotubes Promotes Rapid Kinetics in Sodium Metal – Sulfur Batteries”, Advanced Materials, 2022, 34, 2106572
  23. H. Hao, T. Hutter, B. Boyce, J. Watt, P. Liu, D. Mitlin, “Review of Multifunctional Separators: Stabilizing the Cathode and the Anode for Alkali (Li, Na, and K) Metal–Sulfur and Selenium Batteries”, Chemical Reviews, 2022, 122, 9, 8053–8125
  24. X. Feng, H. Fang, N. Wu, P. Liu, P. Jena, J. Nanda, D. Mitlin, “Review of modification strategies in emerging inorganic solid-state electrolytes for lithium, sodium, and potassium batteries”, Joule,  6(3), 543-587
  25. Y. Wang, H. Dong, N. Katyal, H. Hao, P. Liu, H. Celio, G. Henkelman, J. Watt, D. Mitlin, “A Sodium–Antimony–Telluride Intermetallic Allows Sodium-Metal Cycling at 100% Depth of Discharge and as an Anode-Free Metal Battery”, Advanced Materials, 2021, 2106005
  26. X. Feng, H. Fang, P. Liu, N. Wu, E. Self, L. Yin, P. Wang, X. Li, P. Jena, J. Nanda, D. Mitlin, “Heavily Tungsten-Doped Sodium Thioantimonate Solid-State Electrolytes with Exceptionally Low Activation Energy for Ionic Diffusion”, Angewandte Chemie, 2021, 60, 26158–26166
  27. P. Liu, H. Hao,H. Celio, J. Cui, M. Ren, Y. Wang, H. Dong, A. Chowdhury, T. Hutter, F. Perras, J. Nanda, J. Watt, D. Mitlin, “Multifunctional Separator Allows Stable Cycling of Potassium Metal Anodes and of Potassium Metal Batteries”, Advanced Materials, 2022, 2105855
  28. Y. Wang, H. Hao, S. Hwang, P. Liu, Y. Xu, J. Boscoboinik, D. Datta, D Mitlin, “Selenium infiltrated hierarchical hollow carbon spheres display rapid kinetics and extended cycling as lithium metal battery (LMB) cathodes”, Journal of Materials Chemistry A, 2021, 9, 18582-18593
  29. Q. Dou, N. Wu, H. Yuan, K. Shin, Y. Tang, D. Mitlin, H. Park, “Emerging trends in anion storage materials for the capacitive and hybrid energy storage and beyond”, Chemical Society Reviews, 2021, 50, 6734-6789
  30. V. Sharma, D. Mitlin, D. Datta, “Understanding the Strength of the Selenium−Graphene Interfaces for Energy Storage Systems“, Langmuir, 2021
  31. Y. Sun, H. Wang, W. Wei, Y. Zheng, L. Tao, Y. Wang, M. Huang, J. Shi, Z. Shi, D. Mitlin, “Sulfur-Rich Graphene Nanoboxes with Ultra-High Potassiation Capacity at Fast Charge: Storage Mechanisms and Device Performance“, ACS Nano, 2020
  32. R. Jain, Y. Yuan, Y. Singh, S. Basu, D. Wang, A. Yang, X. Wang, M. Rong, H. J. Lee, D. Frey, R. Khadka, P. Hundekar, S. O. Kim, F. Han, L. Wang, D. Mitlin, R. Shahbazian‐Yassar, N. Koratkar, “Alloying of Alkali Metals with Tellurene“, Advanced Energy Materials, 2020
  33. K. H. Shin, S. K. Park, P. Nakhanivej, Y. Wang, P. Liu, S. M. Bak, M. S. Choi, D. Mitlin, H. S. Park, “Biomimetic composite architecture achieves ultrahigh rate capability and cycling life of sodium ion battery cathodes”, Applied Physics Reviews, 2020, 7(4): 041410
  34. W. Liu, Z. Chen, Z. Zhang, P. Jiang, Y. Chen, E. Paek, Y. Wang, D. Mitlin,  “Lithium-Activated SnS-Graphene Alternating Nanolayers Enable Dendrite-Free Cycling of Thin Sodium Metal Anodes in Carbonate Electrolyte“, Energy & Environmental Science, 2021
  35. W. Liu, P. Liu, D. Mitlin, “Solid Electrolyte Interphases: Review of Emerging Concepts in SEI Analysis and Artificial SEI Membranes for Lithium, Sodium, and Potassium Metal Battery Anodes”, Advanced Energy Materials, 2020, 10(43): 2070177
  36. W. Liu, P. Liu, D. Mitlin, “Tutorial review on structure–dendrite growth relations in metal battery anode supports“, Chemical Society Reviews, 2020, 49, 7284-7300
  37. K. Yao, Z. Xu, M. Ma, D. Mitlin, J. Li, F. Lu, J. Huang, “Densified Metallic MoS2/Graphene Enabling Fast Potassium‐Ion Storage with Superior Gravimetric and Volumetric Capacities“,  Advanced Functional Materials, 2020: 2001484
  38. M. Wang, H. Yang, K. Shen, H. Xu, W. Wang, Z. Yang, L. Zhang, J. Chen, Y. Huang, M. Chen, D. Mitlin, X. Li, “Stable Lithium Sulfur Battery Based on In Situ Electrocatalytically Formed Li2S on Metallic MoS2–Carbon Cloth Support”, Small Methods, 2020, 4(9): 2000353
  39. P. Liu, Y. Wang, H. Hao, S. Basu, X. Feng, Y. Xu, J. Boscoboinik, J. Nanda, J. Watt, D. Mitlin, “Stable Potassium Metal Anodes with an All-Aluminum Current Collector through Improved Electrolyte Wetting”, Advanced Materials, 2020, 32 2002908
  40. J. Pokrzywinski, D. Aulakh, W. Verdegaal, V.H. Pham, H. Bilan, S. Marble, D. Mitlin, M. Wriedt, “Dry and Wet CO2 Capture from Milk‐Derived Microporous Carbons with Tuned Hydrophobicity”, Advanced Sustainable Systems, 2020, 2000001
  41. M. Wang, J. Zhang, L. Zhang, J. Li, W. Wang, Z. Yang, L. Zhang, Y. Wang, J. Chen, Y. Huang, D. Mitlin, X. Li, “Graphene-like Vanadium Oxygen Hydrate (VOH) Nanosheets Intercalated and Exfoliated by Polyaniline (PANI) for Aqueous Zinc-Ion Batteries (ZIBs)”, ACS Applied Materials & Interfaces, 2020, 12(28): 31564-31574
  42. J. Ding, H. Zhang, W. Fan, C. Zhong, W. Hu, D. Mitlin, “Review of Emerging Potassium–Sulfur Batteries”, Advanced Materials, 2020, 32(23): 1908007
  43. P. Liu, D. Mitlin, “Emerging Potassium Metal Anodes: Perspectives on Control of the Electrochemical Interfaces”, Accounts of Chemical Research, 2020, 53, 1161-1175
  44. X. Li, F. Jiang, K. Qu, Y. Wang, Y. Pan, M. Wang, Y. Liu, H. Xu, J. Chen, Y. Huang, J. Zheng, P. Gao, M. Chen, J. Li, Y. Peng, D. Mitlin, “First Atomic-Scale Insight on Degradation in Lithium Iron Phosphate Cathodes by Transmission Electron Microscopy”, The Journal of Physical Chemistry Letters, 2020, 11, 4608−4617
  45. L. Tao, Y. Yang, H. Wang, Y. Zheng, H. Hao, W. Song, J. Shi, M. Huang, D. Mitlin, “Sulfur-nitrogen rich carbon as stable high capacity potassium ion battery anode: performance and storage mechanisms”, Energy Storage Materials, 2020, 27: 212-225
  46. B. Lee, M. Kim, S. Kim, J. Nanda, S. J. Kwon, H. D. Jang, D. Mitlin, S. W. Lee, “High Capacity Adsorption—Dominated Potassium and Sodium Ion Storage in Activated Crumpled Graphene”, Advanced Energy Materials, 2020, 10(17): 1903280
  47. P. Liu, Y. Wang, Q. Gu, J. Nanda, J. Watt, D. Mitlin, “Dendrite-Free Potassium Metal Anodes in a Carbonate Electrolyte”, Advanced Materials, 2020, 32(7): 1906735
  48. F. A. Perras, S. Hwang, Y. Wang, E. C. Self, P. Liu, R. Biswas, S. Nagarajan, V. H. Pham, Y. Xu, J. A. Boscoboinik, D. Su, J. Nanda, M. Pruski, D. Mitlin, “Site-Specific Sodiation Mechanisms of Selenium in Microporous Carbon Host”,  Nano Letters, 2019, 20(2): 918-928
  49. D. Das, D. Sarkar, S. Nagarajan, D. Mitlin, “Cobalt phosphide (Co2P) encapsulated in nitrogen-rich hollow carbon nanocages with fast rate potassium ion storage”,  Chemical Communications, 2020, 56, 14889-14892
  50. W. Liu, H. Li, J. Jin, Y. Wang, Z. Zhang, Z. Chen, Q. Wang, Y. Chen, E. Paek, D. Mitlin, “Synergy of Epoxy Chemical Tethers and Defect? Free Graphene in Enabling Stable Lithium Cycling of Silicon Nanoparticles”, Angewandte Chemie, 2019, 131(46): 16743-16753
  51. X. Li, Y. Liu, Y. Pan, M. S. Wang, J. Chen, H. Xu, Y. Huang, L. Lau, A. Shan, J. Zheng and D. Mitlin, “Functional SrF2 Coated Separator Enabling Robust and Dendrite-Free Solid Electrolyte Interphase on Lithium Metal Anode”, Journal of Materials Chemistry A, 2019, 7, 21349-21361
  52. J. Ding, H. Zhang, H. Zhou, J. Feng, X. Zheng, C. Zhong, E. Paek, W. Hu, D. Mitlin, “Sulfur-Grafted Hollow Carbon Spheres for Potassium-Ion Battery Anodes”, Advanced Materials, 2019, 31(30): 1900429
  53. V. H. Pham, J. A. Boscoboinik, D. J. Stacchiola, E. C. Self, P. Manikandan, S. Nagarajan, Y. Wang, V. G. Pol, J. Nanda, E. Paek and D. Mitlin, “Selenium-sulfur (SeS) fast charging cathode for sodium and lithium metal batteries”, Energy Storage Materials, 2019, 20: 71-79.
  54. Z. Xu, M. Wu, Z. Chen, C. Chen, J. Yang, T. Feng, E. Paek and D. Mitlin, “Direct Structure-Performance Comparison of All-Carbon Potassium and Sodium Ion Capacitors”, Advanced Science, 2019, 6(12): 1802272
  55. B. Lee, E. Paek, D. Mitlin and S. W. Lee, “Sodium Metal Anodes: Emerging Solutions to Dendrite Growth”, Chemical Reviews, 2019, 119(8): 5416-5460
  56. H. Zhang, X. Xu, H. Wang, Y. Lyu, X. Liu, Y. Zhao, J. Shi, W. Liu, E. Paek and D. Mitlin, “Lithium ion capacitor with identical carbon electrodes yields 6 seconds charging and 100,000 cycles stability with 1% capacity fade”, ACS Sustainable Chemistry and Engineering, 2018, 7(2): 2867-2877
  57. W. Liu, Y. Xia, W. Wang, Y. Wang, J. Jin, Y. Chen, E. Paek and D. Mitlin, “Pristine or Highly Defective? Understanding the Role of Graphene Structure for Stable Lithium Metal Plating”, Advanced Energy Materials, 2019, 9(3): 1802918.
  58. W. Liu, P. Li, W. Wang, D. Zhu, Y. Chen, S. Peng, E. Paek and D. Mitlin, “Directional Flow-Aided Sonochemistry Yields Graphene with Tunable Defects to Provide Fundamental Insight on Sodium Metal Plating Behavior”, ACS Nano, 2018, 12 (18): 12255-12268
  59. X. Li, K. Zhang, D. Mitlin, E. Paek, M. Wang, F. Jiang, Y. Huang, Z. Yang, Y. Gong, L. Gu, W. Zhao, Y. Du and J. Zheng, “Li-rich Li[Li1/6Fe1/6Ni1/6Mn1/2]O2 (LFNMO) cathodes: atomic scale insight on the mechanisms of cycling decay and of the improvement due to cobalt phosphate surface modification”, Small,  2018, 14(40): 1802570
  60. J. Ding, W. Hu, E. Paek and D. Mitlin, “Review of hybrid ion capacitors: from aqueous to lithium to sodium”, Chemical Reviews, 2018, 118, 6457-6498
  61. H. Xie, X. Tan, E. J. Luber, B. C. Olsen, W. P. Kalisvaart, K. L. Jungjohann, D.  Mitlin and J. M. Buriak, “β-SnSb for sodium ion battery anodes: phase transformations responsible for enhanced cycling stability revealed by in situ TEM”, ACS Energy Letters, 2018, 3, 1670-1676
  62. C. Bommier, D. Mitlin and X. Ji, “Internal structure – Na storage mechanisms – electrochemical performance relations in carbons”, Progress in Materials Science, 2018, 97, 170-203
  63. X. Li, K. Zhang, D. Mitlin, Z. Yang, M. Wang, Y. Tang, F. Jiang, Y. Du and J. Zheng, “Fundamental Insight into Zr Modification of Li- and Mn-Rich Cathodes: Combined Transmission Electron Microscopy and Electrochemical Impedance Spectroscopy Study”, Chemistry of Materials, 2018, 8, 2566-2573
  64. J. Ding, H. Zhou, H. Zhang, L. Tong and D. Mitlin, “Selenium impregnated monolithic carbons as free-standing cathodes for high volumetric energy lithium and sodium metal batteries”, Advanced Energy Materials, 2018, 8(8): 1701918

Patents